Almeida, M. Peixoto deMartins, LuisaCarabineiro, S. A. C.Lauterbach, T.Rominger, F.Hashmi, A. S. K.Pombeiro, ArmandoFigueiredo, J. L.2013-11-082013-11-082013ALMEIDA, M. Peixoto de; MARTINS, L. M. D. R. S.; CARABINEIRO, S. A. C. ; LAUTERBACH, T. ; ROMINGER, F.; HASHMI, A. S. K.; POMBEIRO, A. J. L.; FIGUEIREDO, J. L. - Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation. Catalysis Science & Technology. ISSN 2044-4753. Vol. 3, nr. 11 (2013), p. 3056-3069.2044-475310.1039/c3cy00552fhttp://hdl.handle.net/10400.21/2885Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.engSchiff-base complexManganese(III) Salen complexesRay-Absorption spectroscopyWall carbon nanotubesPeroxidative oxidationActivated carbonHydrogen-PeroxideCoordination-compoundsGold(III) complexesRhenium complexesjournal article