Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/4985
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dc.contributor.authorFundo, Joana F.-
dc.contributor.authorFernandes, Rui-
dc.contributor.authorAlmeida, Pedro L.-
dc.contributor.authorCarvalho, Alexandra-
dc.contributor.authorFeio, Gabriel-
dc.contributor.authorSilva, Cristina L. M.-
dc.contributor.authorQuintas, Mafalda A. C.-
dc.date.accessioned2015-08-25T10:41:46Z-
dc.date.available2015-08-25T10:41:46Z-
dc.date.issued2014-02-01-
dc.identifier.citationFUNDO, Joana; [et al] – Molecular mobility, composition and structure analysis in glycerol plasticised chitosan films. Food Chemistry. ISSN: 0308-8146. Vol. 144 (2014), pp. 2-8por
dc.identifier.issn0308-8146-
dc.identifier.issn1873-7072-
dc.identifier.urihttp://hdl.handle.net/10400.21/4985-
dc.description.abstractThis study was developed with the purpose to investigate the effect of polysaccharide/plasticiser concentration on the microstructure and molecular dynamics of polymeric film systems, using transmission electron microscope imaging (TEM) and nuclear magnetic resonance (NMR) techniques. Experiments were carried out in chitosan/glycerol films prepared with solutions of different composition. The films obtained after drying and equilibration were characterised in terms of composition, thickness and water activity. Results show that glycerol quantities used in film forming solutions were responsible for films composition; while polymer/total plasticiser ratio in the solution determined the thickness (and thus structure) of the films. These results were confirmed by TEM. NMR allowed understanding the films molecular rearrangement. Two different behaviours for the two components analysed, water and glycerol were observed: the first is predominantly moving free in the matrix, while glycerol is mainly bounded to the chitosan chain. (C) 2013 Elsevier Ltd. All rights reserved.por
dc.language.isoengpor
dc.publisherElsevier Science LTDpor
dc.rightsclosedAccesspor
dc.subjectEdible filmspor
dc.subjectMicrostructurepor
dc.subjectNMRpor
dc.subjectMolecular dynamicspor
dc.subjectStructure functionpor
dc.subjectWater behaviourpor
dc.titleMolecular mobility, composition and structure analysis in glycerol plasticised chitosan filmspor
dc.typearticlepor
dc.peerreviewedyespor
degois.publication.firstPage2por
degois.publication.lastPage8por
degois.publication.locationOxonpor
degois.publication.titleFood Chemistrypor
degois.publication.volume144por
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S0308814613007334#-
dc.identifier.doi10.1016/j.foodchem.2013.05.127-
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