Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/5106
Título: Growth of (Perylene)(2) [PD(MNT)(2)] crystals
Autor: Afonso, M. L.
Silva, R. A. L.
Matos, M.
Lopes, E. B.
Coutinho, J. T.
Pereira, L. C. J.
Henriques, R. T.
Almeida, M.
Palavras-chave: Electrochemical Growth
Aromatic Compounds
Perylene Salts
Palladium Dithiolates
Molecular Conductors
Density-Wave Dynamics
Dimensional Molecular Conductors
Metals (PER)2M(MNT)2
Magnetic-Properties
Complexes
Perylene
MNT=Maleonitridithiolate
Transport
Family
FE
Data: 1-Fev-2012
Editora: Elsevier
Citação: AFONSO, M. L.; [et al] – Growth of (Perylene)(2) [PD(MNT)(2)] crystals. Journal of Crystal Growth. ISSN: 00220248. Vol. 340, nr. 1 (2012), pp. 56-60
Resumo: The conditions for [pd(mnt)(2)]he growth of [pd(mnt)(2)]Perylene) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals either by chemical oxidation and electrochemical routes are [pd(mnt)(2)]escribed. The electrocrystallisation is limited by close [pd(mnt)(2)]roximity of [pd(mnt)(2)]he oxidation [pd(mnt)(2)]otentials of [pd(mnt)(2)]he [pd(mnt)(2)]erylene [pd(mnt)(2)]onor and [Pd(mnt) [pd(mnt)(2)]] - anion, and [pd(mnt)(2)]epending on [pd(mnt)(2)]he experimental conditions [pd(mnt)(2)]ifferent [pd(mnt)(2)]orphologies can be obtained. [pd(mnt)(2)]Per) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals obtained by elecrocrystallisation were found [pd(mnt)(2)]o be [pd(mnt)(2)]ainly of [pd(mnt)(2)]he β-polymorph with [pd(mnt)(2)]roperties comparable [pd(mnt)(2)]o [pd(mnt)(2)]he Cu, Ni and Pt analogues [pd(mnt)(2)]reviously [pd(mnt)(2)]escribed at variance with [pd(mnt)(2)]hose obtained by chemical oxidation which are [pd(mnt)(2)]ainly of [pd(mnt)(2)]he α-polymorph.
Peer review: yes
URI: http://hdl.handle.net/10400.21/5106
DOI: 10.1016/j.jcrysgro.2011.11.083
ISSN: 00220248
Aparece nas colecções:ISEL - Eng. Quim. Biol. - Artigos

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GROWTH OF (PERYLENE)(2) [PD(MNT)(2)] CRYSTALS.pdf777,01 kBAdobe PDFVer/Abrir    Acesso Restrito. Solicitar cópia ao autor!
Growth of.rep.pdf198,07 kBAdobe PDFVer/Abrir


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