Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/2885
Título: Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation
Autor: Almeida, M. Peixoto de
Martins, Luísa Margarida D. R. S.
Carabineiro, S. A. C.
Lauterbach, T.
Rominger, F.
Hashmi, A. S. K.
Pombeiro, Armando J. L.
Figueiredo, J. L.
Palavras-chave: Schiff-base complex
Manganese(III) Salen complexes
Ray-Absorption spectroscopy
Wall carbon nanotubes
Peroxidative oxidation
Activated carbon
Hydrogen-Peroxide
Coordination-compounds
Gold(III) complexes
Rhenium complexes
Data: 2013
Editora: Royal Soc Chemistry
Citação: ALMEIDA, M. Peixoto de; MARTINS, L. M. D. R. S.; CARABINEIRO, S. A. C. ; LAUTERBACH, T. ; ROMINGER, F.; HASHMI, A. S. K.; POMBEIRO, A. J. L.; FIGUEIREDO, J. L. - Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation. Catalysis Science & Technology. ISSN 2044-4753. Vol. 3, nr. 11 (2013), p. 3056-3069.
Resumo: Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.
Peer review: yes
URI: http://hdl.handle.net/10400.21/2885
ISSN: 2044-4753
Aparece nas colecções:ISEL - Eng. Quim. Biol. - Artigos

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