Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/2745
Título: A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst
Autor: Sutradhar, Manas
Kirillova, Marina V.
Silva, M. Fátima C. Guedes da
Martins, Luísa Margarida D. R. S.
Pombeiro, Armando J. L.
Palavras-chave: Hydrocarbon Oxygenations
Vanadium Complexes
Crystal-Structure
Solid-State
Ligand
2-Naphtols
Compound
Core
DFT
Data: 5-Nov-2012
Editora: Amer Chemical Soc
Citação: SUTRADHAR, Manas; KIRILLOVA, Marina V.; SILVA, M. Fátima C. Guedes da; MARTINS, Luísa M. D. R. S.; POMBEIRO, Armando J. L. - A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst. Inorganic Chemistry. ISSN: 0020-1669. Vol. 51, nr 21, (2012), p. 11229-11231.
Resumo: The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions.
Peer review: yes
URI: http://hdl.handle.net/10400.21/2745
ISSN: 0020-1669
Aparece nas colecções:ISEL - Eng. Quim. Biol. - Artigos

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