Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/2224
Título: On the solubility of three disperse anthraquinone dyes in supercritical carbon dioxide: new experimental data and correlation
Autor: Coelho, José Augusto Paixão
Palavra, António F.
Stateva, Roumiana P.
Palavras-chave: Equation-of-state
Azo dyes
Solids
Fluids
Derivatives
Prediction
Liquids
Density
MPA
Data: 20-Abr-2011
Editora: Amer Chemical SOC
Citação: COELHO, José P.; MENDONÇA, Andrea F.; PALAVRA, Antonio F.; STATEVA, Roumiana P. - On the Solubility of Three Disperse Anthraquinone Dyes in Supercritical Carbon Dioxide: New Experimental Data and Correlation. Industrial & Engineering Chemistry Research. ISSN 0888-5885. Vol. 50, n.º8 (2011) p. 4618-4624.
Resumo: Solubility measurements of quinizarin. (1,4-dihydroxyanthraquinone), disperse red 9 (1-(methylamino) anthraquinone), and disperse blue 14 (1,4-bis(methylamino)anthraquinone) in supercritical carbon dioxide (SC CO2) were carried out in a flow type apparatus, at a temperature range from (333.2 to 393.2) K and at pressures from (12.0 to 40.0) MPa. Mole fraction solubility of the three dyes decreases in the order quinizarin (2.9 x 10(-6) to 2.9.10(-4)), red 9 (1.4 x 10(-6) to 3.2 x 10(-4)), and blue 14 (7.8 x 10(-8) to 2.2 x 10(-5)). Four semiempirical density based models were used to correlatethe solubility of the dyes in the SC CO2. From the correlation results, the total heat of reaction, heat of vaporization plus the heat of solvation of the solute, were calculated and compared with the results presented in the literature. The solubilities of the three dyes were correlated also applying the Soave-Redlich-Kwong cubic equation of state (SRK CEoS) with classical mixing rules, and the physical properties required for the modeling were estimated and reported.
Peer review: yes
URI: http://hdl.handle.net/10400.21/2224
ISSN: 0888-5885
Aparece nas colecções:ISEL - Eng. Quim. Biol. - Artigos



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