Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/1751
Título: A new chemical route to synthesise TM-doped (TM = Co, Fe) TiO2 nanoparticles
Autor: Nunes, Manuel R.
Monteiro, Olinda C.
Castro, Ana L.
Vasconcelos, Duarte A.
Silvestre, A. J.
Palavras-chave: Diluted Magnetic Semiconductors
Co- and Fe-doped TiO2 Anatase Nanocrystallites
Hydrothermal Synthesis
TiCl3
Thin-Films
Titanium-Dioxide
Room-Temperature
Anatase
Semiconductors
Ferromagnetism
Transition
Deposition
Magnetism
Growth
Data: Fev-2008
Editora: Wiley-Blackwell
Citação: Nunes Manuel R, Monteiro Olinda C, Castro Ana L, Vasconcelos Duarte A, Silvestre Antonio J. A new chemical route to synthesise TM-doped (TM = Co, Fe) TiO2 nanoparticles. European Journal of Inorganic Chemistry. 2008: 6, 961-965.
Resumo: Since the discovery of ferromagnetism well above room temperature in the Co-doped TiO2 system, diluted magnetic semiconductors based on TiO2 doped with transition metals have generated great interest because of their potential use in the development of spintronic devices. The purpose of this paper is to report on a new and swift chemical route to synthesise highly stable anatase single-phase Co- and Fe-doped TiO2 nanoparticles, with dopant concentrations of up to 10 at.-% and grain sizes that range between 20 and 30 nm. Complementary structural, microstructural and chemical analyses of the different nanopowders synthesised strongly support the hypothesis that a homogeneous distribution of the dopant element in the substitutional sites of the anatase structure has been achieved. Moreover, UV/Vis diffuse reflectance spectra of powder samples show redshifts to lower energies and decreasing bandgap energies with increasing Co or Fe concentration, which is consistent with n-type doping of the TiO2 anatase matrix. Films of Co-doped TiO2 were successfully deposited onto Si (100) substrates by the dip-coating method, with suspensions of Ti1-xCOxO2 nanoparticles in ethylene glycol. ((C)Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
Peer review: yes
URI: http://hdl.handle.net/10400.21/1751
ISSN: 1434-1948
Aparece nas colecções:ISEL - Física - Artigos

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