Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.21/1295
Título: Solvent effects on solution enthalpies of adamantyl derivatives
Autor: Martins, Filomena
Moreira, Luís
Nunes, Nélson
Leitão, Rúben E.
Palavras-chave: 1-Bromoadamantane
1-Adamantanol
2-Adamantanone
Solution Enthalpy
Multiparametric Equation
Solvent Effects
Tert-Butyl Chloride
Thermodynamic Properties
Hydroxylic Solvents
Solvation
Alcohols
Parameters
Bromide
State
Data: Mai-2010
Editora: Springer
Citação: Martins F, Moreira L, Nunes N, Leitão R E. Solvent effects on solution enthalpies of adamantyl derivatives. Journal of Thermal Analysis And Calorimetry. 2010; 100 (2): 483-491.
Relatório da Série N.º: 2;
Resumo: Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving delta(cav) h (s) as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes' characteristics. New insights on the solution processes under scrutiny are presented.
Peer review: yes
URI: http://hdl.handle.net/10400.21/1295
ISSN: 1388-6150
Aparece nas colecções:ISEL - Eng. Quim. Biol. - Artigos

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